Can I use Hotels.com to book a hotel room for a business trip to Manhattan?

I have a business trip coming up next week, so I was wondering if I could use Hotels.com for booking a hotel room and if I could pay from the corporate account. I am also looking for a hotel that is near the city center, with lots of essential amenities nearby, as I probably won't be doing much sightseeing. Price isn't as important as location and reliability.

Knowing my requirements, would you say Hotels.com is a good choice for business-related trips in terms of hotel options and available payment methods?